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Novel ‘inorganic gel casting’ process for the manufacturing of glass foams

机译:用于制造玻璃泡沫的新型“无机凝胶浇铸”工艺

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摘要

A new technique for the production of glass foams was developed, based on alkali activation and gel casting. The alkali activation of soda-lime waste glass powders allowed for the obtainment of well dispersed concentrated suspensions, undergoing gelification by treatment at low temperature (75 degrees C). An extensive direct foaming was achieved by mechanical stirring of partially gelified suspensions, comprising also a surfactant. The suspensions were carefully studied in terms of rheological behavior, so that the final microstructure (total amount of porosity, cell size) can be directly correlated with the degree of gelification. \udA sintering treatment, at 700-800 degrees C, was finally applied to stabilize the foams, in terms of leaching of alkaline ions. Considering the high overall porosity (88-93%), the newly obtained foams exhibited a remarkable compressive strength, in the range of 1.7-4.8 MPa.
机译:基于碱活化和凝胶流延,开发了一种用于生产玻璃泡沫的新技术。苏打石灰废玻璃粉的碱活化使得能够获得分散良好的浓缩悬浮液,通过在低温(75℃)下处理进行凝胶化。通过机械搅拌还包含表面活性剂的部分胶凝的悬浮液,可实现广泛的直接发泡。根据流变行为对悬浮液进行了仔细研究,以使最终的微观结构(孔隙率的总和,细胞大小)与凝胶化程度直接相关。最后,就浸出碱性离子而言,在700-800摄氏度下进行了烧结处理,以稳定泡沫。考虑到较高的总孔隙率(88-93%),新获得的泡沫在1.7-4.8 MPa的范围内表现出显着的抗压强度。

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